Efeitos de agentes oxidantes e oxigênio dissolvido na descoloração do azo corante acid orange 7 por fotólise e fotocatálise

Química Nova

Adriana Campano Lucilha¹  Keiko Takashima¹ 

[1] ,Universidade Estadual de Londrina Centro de Ciências Exatas Departamento de QuímicaLondrina PR ,Brasil

关键词: acid orange 7;    photolysis;    photocatalysis;   

DOI  :  10.1590/S0100-40422009000600007

来源: SciELO

【 摘 要 】

The decolorization of acid orange 7 azo dye by photolysis and photocatalysis by ZnO was investigated in the presence of oxidants such as NaClO3, NaBrO3, NaIO4, and K2S2O8 in an open reactor at 30 ºC. The decolorization was relatively fast at lower oxidants concentrations and slow rate at larger concentrations, except for persulfate in the photocatalysis. Concerning photolysis the rate constant enhanced gradually, except for chlorate, outreaching the obtained values by photocatalysis, at higher concentrations. The air saturation decreased the rate constant in both processes and indicated that the azo dye can be decolorized without dissolved oxygen in persulfate medium.

【 授权许可】

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