Química Nova | |
Adsorción física sobre sólidos: aspectos termodinámicos | |
Juan Miguel Arias1  Elihu Paternina1  Daniel Barragán1  | |
[1] ,Universidad Nacional de Colombia Facultad de Ciencias Departamento de QuímicaBogotá,Colombia | |
关键词: physical adsorption; Gibbs isotherm; isosteric enthalpy; | |
DOI : 10.1590/S0100-40422009000500046 | |
来源: SciELO | |
【 摘 要 】
A thermodynamic formalism based on the Gibbs Dividing Surface (GDS) for the description of a solid-fluid interface is presented, so that the adsorption layer is understand as a phase and the adsorption process as the transference of components between a 3-dimensional phase and a 2-dimensional one. Using a state equation derived from the Henry's Law, we shall show how the Langmuir isotherm is deduced from de Gibbs isotherm. The GDS is useful also for understanding the release of heat by a system as the adsorption occurs.
【 授权许可】
CC BY-NC
All the contents of this journal, except where otherwise noted, is licensed under a Creative Commons Attribution License
【 预 览 】
Files | Size | Format | View |
---|---|---|---|
RO202005130062854ZK.pdf | 381KB | download |