Dinámica de reacciones unimoleculares en fase gas: Desviaciones del comportamiento estadístico

Química Nova

Emilio Martínez-núñez²  Saulo A. Vázquez¹ 

[1] ,Facultad de Ciencias Lagoas Departamento de Química Física Vigo,España

关键词: reaction dynamics;    classical trajectories;    RRKM calculations;   

DOI  :  10.1590/S0100-40422002000400013

来源: SciELO

【 摘 要 】

The present review summarizes the most relevant results of our research group obtained recently in the field of unimolecular reaction dynamics. The following processes are specifically analyzed: the isomerization, dissociation and elimination in methyl nitrite, the fragmentation reactions of the mercaptomethyl cation, the C-CO dissociation in the acetyl and propionyl radicals, and the decomposition of vinyl fluoride. In all the cases, only state- or energy-selected systems are considered. Special emphasis is paid to the possibility of systems exhibiting non-statistical behavior.

【 授权许可】

CC BY-NC   
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