Unambiguous assessments of reaction paths for selected pericyclic reactions

Química Nova

Richard Francis Langler¹ 

[1] ,Mount Allison University Department of Chemistry ,Canada

关键词: Hückel-Möbius transition states;    correlation diagrams;    Frontier-orbital analyses;    modified Zimmerman-Dewar arguments;   

DOI  :  10.1590/S0100-40422000000500021

来源: SciELO

【 摘 要 】

Four commonplace concerted reactions are examined using (i) correlation diagrams, (ii) frontier molecular orbital analyses for transition states, (iii) Zimmerman-Dewar analyses for transition states and (iv) modified Zimmerman-Dewar analyses for transition states. Only the latter approach is consistently satisfactory.

【 授权许可】

CC BY-NC   
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