Oxidações eletrocatalíticas de álcoois e dióis em meio bifásico utilizando metanossulfonato de CeIV como mediador

Química Nova

L. V. Lavagnoli²  J. M. Madurro²  J. R. Romero¹ 

[1] ,Universidade Federal de Uberlândia Departamento de Química Uberlândia MG

关键词: ceric methanesulphonate;    mediator;    electrocatalytic oxidation;   

DOI  :  10.1590/S0100-40421998000600012

来源: SciELO

【 摘 要 】

Some alcohols and diols were oxidized electrocatalytically in a biphasic system using ceriumIV methanesulphonate as mediator. A mixture of methanesulphonic acid solution and benzene was used and aldehydes, ketones and diacids were some of the principal products obtained with yield varying from 27 to 98%. In several cases selectivity was obtained.

【 授权许可】

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