Synthesis, characterization and thermal decomposition of [Pd2 (C²-dmba) (µ-SO4) (SO2)2]

Química Nova

Antonio Carlos Fávero Caires²  Antonio Eduardo Mauro¹ 

[1] ,UFRGS Instituto de Química Porto Alegre RS

关键词: azido-cyclopalladated;    sulphur dioxide;    reactivity;    thermal decomposition;   

DOI  :  10.1590/S0100-40421998000400003

来源: SciELO

【 摘 要 】

The bridged sulphate complex [Pd2 (C²,dmba) (µ-SO4) (SO2)2] has been obtained by reacting a saturated solution of SO2 in methanol and the cyclometallated compound [Pd(C²,N-dmba)(µ-N3)] 2; (dmba = N,N-dimethylbenzylamine), at room temperature for 24 h. Reaction product was characterized by elemental analysis, NMR comprising 13C{¹H} and ¹H nuclei and I.R. spectrum's measurements. Thermal behavior has been investigated and residual products identified by X-ray powder diffraction.

【 授权许可】

CC BY-NC   
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