Polymerization Mechanism of α,α’-bis(Tetrahydrothiophenio)-β-xylene Dichloride

Molecules

Marcela Almassio¹ 

[1] INIQO, Universidad Nacional del Sur, Avenida Alem 1253, 8000 Bahía Blanca, Argentina

关键词: conjugated polymers;    poly(phenylene vinylene);    precursor route;   

DOI  :  10.3390/50300596

来源: mdpi

【 摘 要 】

A experimental study was performed regarding the influence of the base nature and solvent on the reactive intermediate concentration in the base-promoted bissulfonium salts polymerization. Such polymerization reaction is part of a synthetic procedure used to prepare conjugated polymers. In addition, a theoretical study suggest that a one-electron transfer could be involved in the initiation step.

【 授权许可】

CC BY   
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.