The Prognostication of Columnar Mesophases - Synthesis and Mesomorphism of Some Porphyrin Derivatives

Molecules

Olga B. Akopova¹ 

[1]¹Ivanovo State University, 39, Ermak st., Ivanovo, 153000, Russian Federation[2] height:6px

[3]"> ²Institute of the Solution Chemistry of Russian Academy of Sciences, Akademicheskaya, 1, 153045, Ivanovo, Russian Federation

关键词: Porphyrin;    mesomorphism;    liquid crystals;   

DOI  :  10.3390/50600797

来源: mdpi

【 摘 要 】

The existence of columnar mesophases (CM) for a new series of the porphyrin derivatives is predicted. With this purpose, the computation of molecular parameters (K, К_c, К_s, K_p, M_m, M_r) is carried out for eighty five molecules, including materials with a small number of peripheral substitutes. For verification of the existence of CM in the series of materials examined, some of them are synthesized and their mesomorphism is investigated.

【 授权许可】

CC BY   
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.