Synthetic Studies on Diels-Alder Adducts: Intramolecular Interactions Between Two Functions

Molecules

Mauricio Gomes Constantino¹  Altamiro Xavier De Souza¹ 

[1] Departamento de Química, Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Av. Bandeirantes 3900, 14040-901 – Ribeirão Preto – SP, Brazil

关键词: Diels-Alder adducts;    Intramolecular interactions;    1;    4-Diols oxidation;    Cyclic phosphite;   

DOI  :  10.3390/70600475

来源: mdpi

【 摘 要 】

In this paper we describe the synthesis of a γ,δ-unsaturated aldehyde from a bicyclic Diels-Alder adduct, to be used in future electrocyclic reaction studies. A number of reactions produced undesired materials resulting from the interaction between functions, forcing the use of partial protection to accomplish a synthesis that would be otherwise straightforward. Suggestions to account for the results are given.

【 授权许可】

CC BY   
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.