Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates†

Molecules

Thomas Netscher¹ 

关键词: Alkylation reagents;    S_N2 substitution reactions;    steric hindrance;    sulfonic esters;    sulfur-oxygen bond cleavage;   

DOI  :  10.3390/70800601

来源: mdpi

【 摘 要 】

The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed.

【 授权许可】

Unknown   
© 2002 by MDPI (http://www.mdpi.org).