Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

Molecules

Maria Daoudi²  Najib Ben Larbi²  Driss Benjelloun²  Abdelali Kerbal²  Jean Pierre Launay¹  Jacques Bonvoisin¹  Joël Jaud¹  Mostafa Mimouni³ 

[1] CEMES, CNRS, 29, rue Jeanne Marvig, 31055 Toulouse Cedex 04, France;Département de Chimie, Faculté des Sciences, Dhar El Mehraz, 50000 Fés, Morocco;Département de Chimie, Faculté des Sciences, 60000 Oujda, Morocco

关键词: Structure;    tripod;    pyrazole;    tridentate;    flexible ligand;   

DOI  :  10.3390/70900690

来源: mdpi

【 摘 要 】

The tripodal ligand N,N-bis-(3-carbomethoxy-5-methylpyrazol-1-yl)methyl aniline (2) has been prepared by the condensation of aniline with two equivalents of N-hydroxymethyl[3-carbomethoxy-5-methyl]pyrazole. The molecule consists of two structurally analogous 3-carbomethoxy-5-methylpyrazol-1-ylmethyl moieties, which adopt a transoidal conformation via a central aniline ring, suggesting that this tripodal ligand is highly flexible and could accommodate many metals by coordination.

【 授权许可】

Unknown   
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