Regioselective Ethanolamination and Ketalization of 3-Ph-2,4-diacetyl(diethoxycarbonyl)-5-hydroxy-5-methylcyclohexanones

Molecules

Adele P. Krivenko¹  Eleanor A. Kozlova¹  Alexander V. Grigorev¹ 

[1] id="af1-molecules-08-00251">Chair of Organic and Bioorganic Chemistry, Saratov State University, 83 Astrakhanskaya Str., Saratov 410026, Russ

关键词: Cyclohexanones;    ethanolamine;    ethylene glycol;    enaminoketones;    heterospirans;   

DOI  :  10.3390/80200251

来源: mdpi

【 摘 要 】

The reaction of 3-phenyl-2,4-diacetyl(diethoxycarbonyl)-5-hydroxy-5-methyl-cyclohexanones with ethanolamine and ethylene glycol proceeds regioselectively using the carbonyl group of the alicycle to produce the corresponding cyclohexenylethanolamines and dioxolanes.

【 授权许可】

Unknown   
© 2003 by MDPI (http://www.mdpi.org).