From Labdanes to Drimanes. Degradation of the Side Chain of Dihydrozamoranic Acid.

Molecules

Jesús M. L. Rodilla¹  D. Dໞz²  J. G. Urones² 

[1] Departamento de Química, Universidade da Beira Interior, 6201-001 Covilhã, Portugal. Fax: [phone]; Tel: [phone];Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad de Salamanca, 37008 Salamanca, Spain. Fax: [phone]; Tel: [phone]; E-mail:

关键词: Dihidrozamoranic acid;    drimane derivatives;    antifeedant;   

DOI  :  10.3390/90500300

来源: mdpi

【 摘 要 】

A new route for the degradation of the saturated side chain of dihydrozamoranic acid has been devised, giving an advanced intermediate, compound 14, useful for the synthesis of insect antifeedants such as warburganal and polygodial.

【 授权许可】

Unknown   
© 2004 by MDPI (http://www.mdpi.org).