Behavior of the Thermodynamic Properties of Binary Mixtures near the Critical Azeotrope

Entropy

关键词: azeotropic mixtures;    critical line;    mole fraction;    equation of state;   

DOI  :  10.3390/e5040348

来源: mdpi

【 摘 要 】

In this work we investigate the critical line of binary azeotropic mixtures of acetone-n-pentane. We pinpoint the abnormal behavior of the critical density line as a function of the mole fraction of one of the component and show its influence on other thermodynamic properties such as the volume, the enthalpy and the entropy.

【 授权许可】

CC BY   
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.