Molecules | |
Influence of the Dielectric Medium on the Carbonyl Infrared Absorption Peak of Acetylferrocene | |
Ysas J. Alvarado1  José Lucas Pe༚-Suárez1  Néstor Cubillán1  Paola H. Labarca1  José A. Caldera-Luzardo1  | |
[1]Laboratorio de Electrónica Molecular, Departamento de Química, Facultad Experimental de Ciencias, La Universidad del Zulia, Ap. 526, Grano de Oro, Módulo No.2, Maracaibo, Venezuela Fax: (+58) 261 7598125 | |
[2] Tel: (+58) 261 7598125 | |
关键词: Frequency shift; SCRF-MO model; acetylferrocene; | |
DOI : 10.3390/10020457 | |
来源: mdpi | |
【 摘 要 】
The solvent effect on the position of the carbonyl vibrational stretching of acetylferrocene in aprotic media was studied in this work. The solvent-induced shifts in this organometallic compound were interpreted in terms of the alternative reaction field model (SCRF-MO) proposed by Kolling. In contrast to the established trends for carbonyl groups in organic systems, the results suggest that the continuum models for the reaction field are not adequate and that the influence of dipolarity-polarizability described by an inhomogeneous coupling function
【 授权许可】
Unknown
© 2005 by MDPI (
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RO202003190060207ZK.pdf | 273KB | download |