Synthesis Reactions of N-Methylbenzylammonium Fluorochromate(VI) on Silica Gel a Selective Efficient Heterogeneous Oxidant

Molecules

M. Z. Kassaee¹  S. Z. Sayyed-Alangi² 

[1] id="af1-molecules-09-00825">Department of Chemistry, Tarbiat Modarres University, P.O. Box 14155-4838, Tehran, Iran; Fax: [phone]

关键词: N-Methylbenzylammonium fluorochromate(VI);    heterogeneous oxidants;    silica gel;    oxidation;    alcohols;   

DOI  :  10.3390/91000825

来源: mdpi

【 摘 要 】

N-Methylbenzylammonium fluorochromate(VI) (MBAFC) is easily synthesized by addition of N-methylbenzylamine to an aqueous solution of CrO₃ and HF. MBAFC shows selectivity in the oxidation of aryl alcohols to their corresponding aldehydes and ketones under mild conditions. The durability, ease of work up and efficiency of MBAFC are considerably increased upon its absorption on silica gel.

【 授权许可】

Unknown   
2004 by MDPI (http:www.mdpi.org).