Polymer – Supported Cobalt (II) Catalysts for the Oxidation of Alkenes

Molecules

Edyta Bᐪż¹ 

[1]id="af1-molecules-11-00115">Department of Polymer Science and Technology, Krakow University of Technology, ul. Warszawska 24, 31-155 Krakow, Poland. Fax: [phone]

关键词: Epoxidation;    cobalt complexes;    polyaniline based-catalysts;    conjugated-polymers;    catalysts;   

DOI  :  10.3390/11010115

来源: mdpi

【 摘 要 】

Polymer-supported heterogeneous catalysts in a form of complexes of 8-hydroxy-quinoline with cobalt acetate were synthesized. Conjugated polymers – polyaniline (PANI), poly-o-toluidine (POT), poly-o-anisidine (POA) – were used as supports. Oxidation reactions of aliphatic and aromatic hydrocarbons were carried out in the presence of molecular oxygen at atmospheric pressure and epoxides or ketones were obtained as the main products with high selectivity.

【 授权许可】

Unknown   
© 2006 by MDPI (http://www.mdpi.org).