Rotational Spectra of Symmetric Top Molecules in Ground and Different Vibrational Excited States, and Phenomenon of Resonance – Applying in CF3CCH

International Journal of Molecular Sciences

关键词: excited states;    resonance;    CF₃CCH;    symmetric top molecules;   

DOI  :  10.3390/i8040316

来源: mdpi

【 摘 要 】

This paper deals with review of exploration of resonance in symmetric top molecules in different vibrational excited states, v_t = n (n =1, 2, 3, 4). Calculations for CF₃CCH shows that resonance take place atfor v₁₀ = 2 and v₁₀ = 3 respectively. In order to account for splitting about 3 MHz for the − 2 series in v₁₀ = 4 is necessary to introduce the element 〈 J,k, ℓ|f₂₄| J,k + 2, ℓ − 4〉 in fitting program.

【 授权许可】

Unknown   
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