International Journal of Molecular Sciences | |
Correlations of the Specific Rates of Solvolysis of Aromatic Carbamoyl Chlorides, Chloroformates, Chlorothionoformates, and Chlorodithioformates Revisited | |
Dennis N. Kevill2  Fumie Koyoshi1  | |
[1] Department of Chemistry, Wesley College, 120 N. State Street, Dover, Delaware 19901-3875, USA; E-mail:;Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, Illinois 60115-2862, USA; E-mail: | |
关键词:
solvolysis;
carbamoyl chlorides;
chloroformates;
chlorothionoformates;
chlorodithioformates;
Grunwald-Winstein equation;
aromatic ring parameter ( |
|
DOI : 10.3390/i8040346 | |
来源: mdpi | |
【 摘 要 】
Additional specific rates of solvolysis are determined for phenyl chloroformate. These values are combined with literature values to give a total of 49 data points, which are used within simple and extended Grunwald-Winstein treatments. Literature values are also brought together to allow treatments in more solvents than previously for three
【 授权许可】
Unknown
© 2007 by MDPI
【 预 览 】
Files | Size | Format | View |
---|---|---|---|
RO202003190059404ZK.pdf | 231KB | download |