Molecules | |
Synthesis and Properties of Novel Unsymmetrical Donor Molecules Containing |
|
Lakhemici Kaboub1  Slimane Fradj1  | |
[1] id="af1-molecules-11-00776">Laboratoire des Matériaux Organiques et Hétérochimie, Département de Chimie, Université de Tébessa, 12000 Tébessa, Alger | |
关键词: Tetratiafulvalene; voltammetry; organic materials; conductivity; degree of charge transfer; | |
DOI : 10.3390/11100776 | |
来源: mdpi | |
【 摘 要 】
We report the synthesis and properties of eight new tetrathiafulvalene (TTF) derivatives containing two different functionalities, prepared with the aim of obtaining stable organic materials. The four acetoxyphenyl- and four hydroxyphenyl TTFs were synthesized via Wittig-type condensations. The electrochemical properties of these redox-active molecules were studied by cyclic voltammetry. Charge transfer complexes with tetracyanoquinodimethane (TCNQ) were prepared by chemical redox reactions. The complexes have been proven to give conducting materials. The UV-VIS and IR spectra of the TCNQ salts were recorded and used to characterize and estimate the degree of charge transfer of these complexes.
【 授权许可】
Unknown
© 2006 by MDPI (http://www.mdpi.org).
【 预 览 】
Files | Size | Format | View |
---|---|---|---|
RO202003190059366ZK.pdf | 87KB | download |