Aqueous Ti(IV)-Catalyzed Diels-Alder Reaction

Molecules

关键词: Diels-Alder reaction;    aqueous;    cyclohexadiene;    benzoquinone;    Lewis acid catalysis;    green chemistry;    water-soluble Lewis acid catalyst;   

DOI  :  10.3390/12081674

来源: mdpi

【 摘 要 】

The aqueous Diels-Alder reaction of 1,3-cyclohexadiene with 1,4-benzoquinone was compared and contrasted to the same reaction catalyzed with Flextyl P™, a novel Ti(IV) performance catalyst. The catalyst improved conversion by 22% versus the uncatalyzed reaction and represents a rare example of a Ti(IV) catalyzed Diels-Alder reaction in water.

【 授权许可】

Unknown   
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