期刊论文详细信息
Molecules
Reaction of Nitrilimines with 2-Substituted Aza-heterocycles. Synthesis of Pyrrolo[1,2-a]pyridine and Pyrimido[2,1-d]1,2,3,5- tetrazine
Adel M. Awadallah1 
[1] Chemistry Department, Faculty of Science, Islamic University of Gaza, P. O. Box 108, Gaza, Palestine
关键词: Nitrilimines;    ethyl pyridine-2-acetate;    pyrrolo[1;    2-a]pyridine;    2-amino-pyrimidine;    pyrimido[2;    1-d]1;    2;    3;    5-tetrazine;    2-cyanomethylbenzimidazole;    2-amino-benzimidazole;   
DOI  :  10.3390/molecules13010170
来源: mdpi
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【 摘 要 】

The reaction of nitrilimine 6a with ethyl pyridine-2-acetate (7) gave the corresponding pyrrolo[1,2-a]pyridine 8, while the reaction of 6b containing an ester moiety afforded the acyclic adduct 9. The reaction of 6a with 2-aminopyrimidine (10) gave the novel unexpected pyrimido[2,1-d]1,2,3,5-tetrazine 11. Acyclic adducts 16 and 17 were obtained from the reaction of 6b with 2-cyanomethylbenzimidazole (14) and 2-aminobenzimidazole (15), respectively.

【 授权许可】

Unknown   
© 2008 by MDPI (http://www.mdpi.org).

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