期刊论文详细信息
Molecules | |
Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones | |
Satoru Matsukawa1  Izumi Sekine1  | |
[1] Department of Science Education, Faculty of Education, Ibaraki University, Ibaraki, 310-8512 Japan | |
关键词: organocatalysis; cyanosilylaton; cyanohydrin carbonate; phosphines; cyanation; | |
DOI : 10.3390/molecules14093353 | |
来源: mdpi | |
【 摘 要 】
A variety of aldehydes and ketones were transformed to their corresponding cyanohydrin silyl ethers in good to excellent yields in the presence of 1-5 mol% of tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP). Cyanohydrin carbonates were also readily prepared using 5-10 mol% of TTMPP as an organocatalyst.
【 授权许可】
CC BY
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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