Modeling Electric Discharges with Entropy Production Rate Principles

Entropy

关键词: entropy production rate principles;    Steenbeck principle;    Prigogine principle;    electric arc;    charge injection;   

DOI  :  10.3390/e11041042

来源: mdpi

【 摘 要 】

Under which circumstances are variational principles based on entropy production rate useful tools for modeling steady states of electric (gas) discharge systems far from equilibrium? It is first shown how various different approaches, as Steenbeck’s minimum voltage and Prigogine’s minimum entropy production rate principles are related to the maximum entropy production rate principle (MEPP). Secondly, three typical examples are discussed, which provide a certain insight in the structure of the models that are candidates for MEPP application. It is then thirdly argued that MEPP, although not being an exact physical law, may provide reasonable model parameter estimates, provided the constraints contain the relevant (nonlinear) physical effects and the parameters to be determined are related to disregarded weak constraints that affect mainly global entropy production. Finally, it is additionally conjectured that a further reason for the success of MEPP in certain far from equilibrium systems might be based on a hidden linearity of the underlying kinetic equation(s).

【 授权许可】

CC BY   
© 2009 by the author; licensee Molecular Diversity Preservation International, Basel, Switzerland.