期刊论文详细信息
Materials | |
Dinitrogen and Related Chemistry of the Lanthanides: A Review of the Reductive Capture of Dinitrogen, As Well As Mono- and Di-aza Containing Ligand Chemistry of Relevance to Known and Postulated Metal Mediated Dinitrogen Derivatives | |
Michael G. Gardiner1  | |
关键词: lanthanide; nitrogen reduction; nitrogen fixation; organolanthanide; imide; dinitrogen complexes; azobenzene reduction; | |
DOI : 10.3390/ma3020841 | |
来源: mdpi | |
【 摘 要 】
This paper reviews the current array of complexes of relevance to achieving lanthanide mediated nitrogen fixation. A brief history of nitrogen fixation is described, including a limited discussion of successful transition metal facilitated nitrogen fixation systems. A detailed discussion of the numerous lanthanide-nitrogen species relevant to nitrogen fixation are discussed and are related to the Chatt cycle for nitrogen fixation.
【 授权许可】
CC BY
© 2010 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland.
【 预 览 】
Files | Size | Format | View |
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RO202003190055021ZK.pdf | 680KB | download |