Pd(II)/HPMoV-Catalyzed Direct Oxidative Coupling Reaction of Benzenes with Olefins

Molecules

Yasushi Obora¹ 

[1] Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering and High Technology Research Center, Kansai University, Suita, Osaka 564-8680, Japan

关键词: direct coupling;    oxidative coupling;    arenes;    molybdovanadophosphoric acid;   

DOI  :  10.3390/molecules15031487

来源: mdpi

【 摘 要 】

The direct aerobic coupling reaction of arenes with olefins was successfully achieved by the use of Pd(OAc)₂/molybdovanadophosphoric acid (HPMoV) as a key catalyst under 1 atm of dioxygen. This catalytic system could be extended to the coupling reaction of various substituted benzenes with olefins such as acrylates, aclrolein, and ethylene through the direct aromatic C-H bond activation.

【 授权许可】

CC BY   
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.