Synthesis, Characterization and Reactivity Ratio Study of Poly(di(tri-n-butyltin) citraconate-co-N-vinylimidazole)

Molecules

Salem S. Al-Deyab¹  Mohamed H. El-Newehy¹ 

[1] Petrochemical Research Chair, Chemistry Department, College of Science, King Saud University, Riyadh 11451, P.O. Box 2455, Saudi Arabia

关键词: bis(tri-n-butyltin) oxide;    citraconate;    N-vinyl imidazole;    reactivity ratio;   

DOI  :  10.3390/molecules15074750

来源: mdpi

【 摘 要 】

The organotin monomer di(tri-n-butyltin) citraconate (DTBTC, I) was synthesized. Subsequently this monomer was copolymerized with N-vinylimidazole (VI) using a free radical technique. The overall conversion was kept low (≤14% wt/wt) for all studied samples and the copolymer composition was determined from tin analysis using the Gilman and Rosenberg method. The synthesized monomer and copolymer were further characterized by elemental analysis, ¹H- and ¹³C-NMR, and FTIR spectroscopy.

【 授权许可】

CC BY   
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.