International Journal of Molecular Sciences | |
Analysis of the Nucleophilic Solvation Effects in Isopropyl Chlorothioformate Solvolysis | |
Malcolm J. D’Souza1  Brian P. Mahon1  | |
[1] Department of Chemistry, Wesley College, 120 N. State Street, Dover, DE 19901-3875, USA | |
关键词: solvolysis; Grunwald-Winstein Equations; nucleophilic solvation; chlorothioformate; | |
DOI : 10.3390/ijms11072597 | |
来源: mdpi | |
【 摘 要 】
Correlation of the solvent effects through application of the extended Grunwald-Winstein equation to the solvolysis of isopropyl chlorothioformate results in a sensitivity value of 0.38 towards changes in solvent nucleophilicity (
【 授权许可】
CC BY
© 2010 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland.
【 预 览 】
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RO202003190053049ZK.pdf | 222KB | download |