Recent Applications of Polymer Supported Organometallic Catalysts in Organic Synthesis

Molecules

关键词: polymer supported;    organometallic;    solid phase synthesis;    cross-coupling;    metathesis;    allylic substitution;    transfer hydrogenation;    aryl amination;   

DOI  :  10.3390/molecules15096306

来源: mdpi

【 摘 要 】

Recent developments concerning the application of polymer supported organometallic reagents in solid phase synthesis are reviewed, with a special focus on methodology for carbon-carbon formation. Examples of reactions that are covered include the classical Suzuki, Sonogashira and Heck coupings, but also aryl amination, epoxide opening, rearrangements, metathesis and cyclopropanation. Applications in the field of asymmetric synthesis are also discussed.

【 授权许可】

CC BY   
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.