Polymers | |
Chemically Induced Dynamic Nuclear Polarization during the Thermolysis of Alkoxyamines: A New Approach to Detect the Occurrence of H-Transfer Reactions | |
Maria Edeleva1  Sylvain R. A. Marque2  Denis Bertin2  Didier Gigmes2  Yohann Guillaneuf2  | |
[1] Physical Chemistry Department, Novosibirsk State University, Novosibirsk, Russia; E-Mail:;UMR 6264-LCP, CNRS-Aix-Marseille Université, case 521, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France; E-Mails: | |
关键词: nitroxide mediated polymerization; alkoxyamines; H-transfer reactions; CIDNP; | |
DOI : 10.3390/polym2040364 | |
来源: mdpi | |
【 摘 要 】
Thermal decomposition of alkoxyamines in the presence of scavengers was found to proceed with the formation of chemically induced nuclear polarization detected by 1H NMR. The distinctive Chemically Induced Dynamic Nuclear Polarization (CIDNP) features were studied using the example of three alkoxyamines: 4-nitrophenyl 2-(2,2,6,6-tetramethylpiperidin-1-yloxy)-2-methylpropanoate (
【 授权许可】
CC BY
© 2010 by the authors; licensee MDPI, Basel, Switzerland.
【 预 览 】
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RO202003190052133ZK.pdf | 999KB | download |