Recent Applications of the (TMS)3SiH Radical-Based Reagent

Molecules

Chryssostomos Chatgilialoglu¹ 

[1]¹ISOF, Consiglio Nazionale delle Ricerche, 40129 Bologna, Italy[2] height:6px

[3]"> ²Institut de Science des Matériaux de Mulhouse IS2M, LRC CNRS 7228-ENSCMu-UHA, 15, rue Jean Starcky, 68057 Mulhouse Cedex, France

关键词: tris(trimethylsilyl)silane;    radical reactions;    silyl radical;    reduction;    hydrosilylation;    photopolymerization;   

DOI  :  10.3390/molecules17010527

来源: mdpi

【 摘 要 】

This review article focuses on the recent applications of tris(trimethylsilyl)silane as a radical-based reagent in organic chemistry. Numerous examples of the successful use of (TMS)₃SiH in radical reductions, hydrosilylation and consecutive radical reactions are given. The use of (TMS)₃SiH allows reactions to be carried out under mild conditions with excellent yields of products and remarkable chemo-, regio-, and stereoselectivity. The strategic role of (TMS)₃SiH in polymerization is underlined with emphasis on the photo-induced radical polymerization of olefins and photo-promoted cationic polymerization of epoxides.

【 授权许可】

CC BY   
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.