Controlled Photoradical Polymerization Mediated by 2,2,6,6-Tetramethylpiperidine-1-Oxyl

Polymers

关键词: controlled photoradical polymerization;    2;    2;    6;    6-tetramethylpiperidine-1-oxyl;    azoinitiators;    photo-acid generators;    methyl methacrylate;   

DOI  :  10.3390/polym4021125

来源: mdpi

【 摘 要 】

In recent years, controlled photoradical polymerization has been established using 2,2,6,6-tetramethylpiperidine-1-oxyl as a mediator. This review article will describe the molecular weight control, polymerization mechanism, influence of initiator structure, effect of substituents supported on photo-acid generator, stability of the propagating chain end, photo-latency of the polymerization, molecular design, and an application to heterogeneous polymerization in an alcoholic medium.

【 授权许可】

CC BY   
© 2012 by the authors; licensee MDPI, Basel, Switzerland.