Crystals | |
Single-Crystal-to-Single-Crystal Transformation from δ-(BEDT-TTF)4[OsNOCl5]1.33(C6H5NO2)0.67 to β"-(BEDT-TTF)3[OsNOCl5] | |
Leokadiya Zorina2  Sergey Simonov2  Enric Canadell1  | |
[1] Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus de la UAB, Bellaterra 08193, Spain;Institute of Solid State Physics RAS, Chernogolovka MD 142432, Russia; | |
关键词: single-crystal-to-single-crystal transformation; low-dimensional organic conductors; BEDT-TTF; photochromic octahedral anion; single crystal structure; electronic band structure; | |
DOI : 10.3390/cryst2020627 | |
来源: mdpi | |
【 摘 要 】
We report on the single-crystal-to-single-crystal transformation occurring over time in a layered organic molecular conductor based on BEDT-TTF. The process is connected with removal of solvent molecules from the complex anion layer resulting in concomitant partial irreversible conversion of the δ-(BEDT-TTF)4[OsNOCl5]1.33(C6H5NO2)0.67 structure to the β"-(BEDT-TTF)3[OsNOCl5] structure. Along with symmetry lowering from
【 授权许可】
CC BY
© 2012 by the authors; licensee MDPI, Basel, Switzerland.
【 预 览 】
Files | Size | Format | View |
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RO202003190043589ZK.pdf | 1345KB | download |