Continuous Process for Biodiesel Production in Packed Bed Reactor from Waste Frying Oil Using Potassium Hydroxide Supported on Jatropha curcas Fruit Shell as Solid Catalyst

Applied Sciences

Achanai Buasri¹  Nattawut Chaiyut¹  Vorrada Loryuenyong¹  Chao Rodklum¹  Techit Chaikwan¹ 

[1] Department of Materials Science and Engineering, Faculty of Engineering and Industrial Technology, Silpakorn University, Nakhon Pathom 73000, Thailand;

关键词: biodiesel;    packed bed reactor;    waste frying oil;    Jatropha curcas fruit shell;   

DOI  :  10.3390/app2030641

来源: mdpi

【 摘 要 】

The transesterification of waste frying oil (WFO) with methanol in the presence of potassium hydroxide catalyst supported on Jatropha curcas fruit shell activated carbon (KOH/JS) was studied. The catalyst systems were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and the Brunauer–Emmett–Teller (BET) method. The effects of reaction variables such as residence time, reaction temperature, methanol/oil molar ratio and catalyst bed height in packed bed reactor (PBR) on the yield of biodiesel were investigated. SEM images showed that KOH was well distributed on the catalyst support. The optimum conditions for achieving the conversion yield of 86.7% consisted of a residence time of 2 h, reaction temperature of 60 °C, methanol/oil molar ratio of 16 and catalyst bed height of 250 mm. KOH/JS could be used repeatedly five times without any activation treatment, and no significant activity loss was observed. The results confirmed that KOH/JS catalyst had a great potential to be used for industrial application in the transesterification of WFO. The fuel properties of biodiesel were also determined.

【 授权许可】

CC BY   
© 2012 by the authors; licensee MDPI, Basel, Switzerland.