Solid-State NMR Spectroscopy of Metal–Organic Framework Compounds (MOFs)

Materials

Herbert C. Hoffmann²  Marta Debowski²  Philipp Müller¹  Silvia Paasch²  Irena Senkovska¹  Stefan Kaskel¹ 

[1] Department of Chemistry and Food Chemistry, Inorganic Chemistry I, Dresden University of Technology, Dresden 01062, Germany; E-Mails:;Department of Chemistry and Food Chemistry, Bioanalytical Chemistry, Dresden University of Technology, Dresden 01062, Germany; E-Mails:

关键词: metal–organic frameworks;    porous materials;    solid-state NMR;    host–guest interactions;    ¹²⁹Xe NMR;   

DOI  :  10.3390/ma5122537

来源: mdpi

【 摘 要 】

Nuclear Magnetic Resonance (NMR) spectroscopy is a well-established method for the investigation of various types of porous materials. During the past decade, metal–organic frameworks have attracted increasing research interest. Solid-state NMR spectroscopy has rapidly evolved into an important tool for the study of the structure, dynamics and flexibility of these materials, as well as for the characterization of host–guest interactions with adsorbed species such as xenon, carbon dioxide, water, and many others. The present review introduces and highlights recent developments in this rapidly growing field.

【 授权许可】

CC BY   
© 2012 by the authors; licensee MDPI, Basel, Switzerland.