International Journal of Molecular Sciences | |
Spectral Inverse Quantum (Spectral-IQ) Method for Modeling Mesoporous Systems: Application on Silica Films by FTIR | |
Ana-Maria Putz1  | |
[1] Institute of Chemistry Timisoara of the Romanian Academy, 24 Mihai Viteazul Bld, Timişoara, RO-300223, Romania; E-Mail: | |
关键词: particle-wave quantum ratio; sol-gel synthesis; FT-IR spectra; TO4 IR absorption band; ionic liquid-like cosurfactants; | |
DOI : 10.3390/ijms131215925 | |
来源: mdpi | |
【 摘 要 】
The present work advances the inverse quantum (IQ) structural criterion for ordering and characterizing the porosity of the mesosystems based on the recently advanced ratio of the particle-to-wave nature of quantum objects within the extended Heisenberg uncertainty relationship through employing the quantum fluctuation, both for free and observed quantum scattering information, as computed upon spectral identification of the wave-numbers specific to the maximum of absorption intensity record, and to left-, right- and full-width at the half maximum (FWHM) of the concerned bands of a given compound. It furnishes the hierarchy for classifying the mesoporous systems from more particle-related (porous, tight or ionic bindings) to more wave behavior (free or covalent bindings). This so-called spectral inverse quantum (Spectral-IQ) particle-to-wave assignment was illustrated on spectral measurement of FT-IR (bonding) bands’ assignment for samples synthesized within different basic environment and different thermal treatment on mesoporous materials obtained by sol-gel technique with
【 授权许可】
CC BY
© 2012 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland.
【 预 览 】
Files | Size | Format | View |
---|---|---|---|
RO202003190040714ZK.pdf | 559KB | download |