Materials | |
Mechanism of Catalytic Water Oxidation by the Ruthenium Blue Dimer Catalyst: Comparative Study in D2O |
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Dooshaye Moonshiram1  Vatsal Purohit1  Javier J. Concepcion2  Thomas J. Meyer2  | |
[1] Department of Physics, Purdue University, 525 Northwestern West Lafayette, IN 47907, USA; E-Mails:;Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599, USA; E-Mails: | |
关键词: Ru complexes; catalysis of water oxidation; deuterium isotope effect; time-resolved X-band EPR spectroscopy; time-resolved resonance Raman; UV-Vis stopped flow kinetics; | |
DOI : 10.3390/ma6020392 | |
来源: mdpi | |
【 摘 要 】
Water oxidation is critically important for the development of energy solutions based on the concept of artificial photosynthesis. In order to gain deeper insight into the mechanism of water oxidation, the catalytic cycle for the first designed water oxidation catalyst,
【 授权许可】
CC BY
© 2013 by the authors; licensee MDPI, Basel, Switzerland.
【 预 览 】
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RO202003190038884ZK.pdf | 952KB | download |