Benzyl 3-deoxy-3-(3,4,5-trimethoxybenzylamino)-β-L-xylopyranoside

Molbank

关键词: epoxide ring-opening;    3;    4;    5-trimethoxybenzylamine;    benzyl 2;    3-anhydro-β-L-ribopyranoside;   

DOI  :  10.3390/M793

来源: mdpi

【 摘 要 】

Reaction of 3,4,5-trimethoxybenzylamine and benzyl 2,3-anhydro-β-L-ribopyranoside in refluxing ethanol produced benzyl 3-deoxy-3-(3,4,5-trimethoxybenzylamino)-β-L-xylopyranoside in 72.5% yield. An attempt to synthesize the title compound by reacting neat 3,4,5-trimethoxybenzylamine with benzyl 2,3-anhydro-β-L-ribopyranoside without a solvent produced a dark brown mixture with several decomposition products. The structure of benzyl 3-deoxy-3-(3,4,5-trimethoxybenzylamino)-β-L-xylopyranoside was determined using elemental analysis, ¹H-NMR and ¹³C-NMR and its conformation is ¹C₄.

【 授权许可】

CC BY   
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