期刊论文详细信息
Polymers | |
Charge-Transfer Complexes Studied by Dynamic Force Spectroscopy | |
Alberto Gomez-Casado2  Arántzazu Gonzalez-Campo2  Yiheng Zhang1  Xi Zhang1  Pascal Jonkheijm2  | |
[1] Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China; E-Mails:;Molecular Nanofabrication Group, MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500AE Enschede, The Netherlands; E-Mails: | |
关键词: charge-transfer complex; dynamic force spectroscopy; methyl viologen; naphthol; pyrene; kinetics; | |
DOI : 10.3390/polym5010269 | |
来源: mdpi | |
【 摘 要 】
In this paper, the strength and kinetics of two charge-transfer complexes, naphthol-methylviologen and pyrene-methylviologen, are studied using dynamic force spectroscopy. The dissociation rates indicate an enhanced stability of the pyrene-methylviologen complex, which agrees with its higher thermodynamic stability compared to naphthol-methylviologen complex.
【 授权许可】
CC BY
© 2013 by the authors; licensee MDPI, Basel, Switzerland.
【 预 览 】
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RO202003190038082ZK.pdf | 2267KB | download |