Click Reactions as a Key Step for an Efficient and Selective Synthesis of d-Xylose-Based ILs

Molecules

Nadège Ferlin¹  Sylvain Gatard¹  Albert Nguyen Van Nhien²  Matthieu Courty³ 

[1] Institut de Chimie Moléculaire de Reims, UMR CNRS 6229, Université de Reims Champagne-Ardenne, Boîte 44, B.P. 1039, Reims F-51687, France; E-Mails:;Laboratoire des Glucides FRE 3517, Université de Picardie Jules Verne, UFR des Sciences, 33 rue Saint Leu, Amiens Cedex 1 80039, France; E-Mail:;Laboratoire de Réactivité et de Chimie des Solides UMR CNRS 7314, Université de Picardie Jules Verne, UFR des Sciences, 33 rue Saint Leu, Amiens Cedex 1 80039, France; E-Mail:

关键词: ionic liquids;    d-xylose;    click chemistry;   

DOI  :  10.3390/molecules180911512

来源: mdpi

【 摘 要 】

d-Xylose-based ionic liquids have been prepared from d-xylose following a five steps reaction sequence, the key step being a click cycloaddition. These ionic liquids (ILs) have been characterized through classical analytical methods (IR, NMR, mass spectroscopy, elemental analysis) and their stability constants, Tg and Tdec, were also determined. Considering their properties and their hydrophilicity, these compounds could be alternative solvents for chemical applications under mild conditions.

【 授权许可】

CC BY   
© 2013 by the authors; licensee MDPI, Basel, Switzerland.