Conductance Studies on Complex Formation between c-Methylcalix[4]resorcinarene and Titanium (III) in Acetonitrile-H2O Binary Solutions

Molecules

Majid Rezayi¹  Yatimah Alias³  Mahnaz M. Abdi²  Kasra Saeedfar⁴ 

[1] Food Quality and Safety Research Department, Food Science and Technology Research Institute, ACECR Mashhad Branch, 91775-1376 Mashhad, Iran;Department of Chemistry, Faculty of Sciences, Universiti Putra Malaysia, 43400 Serdang, Selangor D.E., Malaysia;Chemistry Department, Faculty of Science, University Malaya, 50603 Kuala Lumpur, Malaysia;School of Chemical Sciences and Food Technology, Faculty of Science and Technology, University Kebangsaan Malaysia, 43600 Bangi, Selangor D.E., Malaysia

关键词: conductance data;    calixresorcinarenes;    titanium(III);    c-methylcalix[4]- resorcinarene;    acetonitrile (AN)-water (H₂O);    binary mixtures;   

DOI  :  10.3390/molecules181012041

来源: mdpi

【 摘 要 】

Calixresorcinarenes have proved to be unique molecules for molecular recognition via hydrogen bonding, hydrophobic and ionic interactions with suitable substrates such as cations. The study of the interactions involved in the complexation of different cations with calixresorcinarenes in solvent mixtures is important for a better understanding of the mechanism of biological transport, molecular recognition, and other analytical applications. This article summarizes different aspects of the complexes of the Ti³⁺ metal cation with c-methylcalix[4]resorcinarene (CMCR) as studied by conductometry in acetonitrile (AN)–water (H₂O) binary mixtures at different temperatures. Conductance data show that the metal cation/ligand (ML) stoichiometry of the complexes in solution is 1:1 in all cases. Non-linear behaviour was observed for the variation of logK_f of the complexes vs. the composition of the binary solvent mixtures. Selectivity of CMCR for the Ti³⁺ cation is sensitive to solvent composition; in some cases and at certain compositions of the mixed solvent systems, the selectivity order is changed. Values of thermodynamic parameters (,) for formation of the CMCR–Ti³⁺ complexes in AN–H₂O binary systems were obtained from the temperature dependence of stability constants, and the results show that the thermodynamics of complexation reactions are affected by the nature and composition of the mixed solvents.

【 授权许可】

CC BY   
© 2013 by the authors; licensee MDPI, Basel, Switzerland.