Hexaethylguanidinium Salts

Crystals

Robert Salchner¹  Volker Kahlenberg²  Thomas Gelbrich¹  Klaus Wurst¹  Martin Rauch¹  Gerhard Laus¹ 

[1] Faculty of Chemistry and Pharmacy, University of Innsbruck, 6020 Innsbruck, Austria; E-Mails:;Institute of Mineralogy and Petrography, University of Innsbruck, 6020 Innsbruck, Austria; E-Mail:

关键词: aliquat;    guanidinium;    hexafluorophosphate;    tetrabromocobaltate;    tetrachloro-cuprate;    tetrachloroferrate;    bistriflimide;   

DOI  :  10.3390/cryst4030404

来源: mdpi

【 摘 要 】

Crystal structures of five hexaethylguanidinium salts (PF₆⁻ 1, FeCl₄⁻ 2, CuCl₄²⁻·H₂O 3, CoBr₄²⁻/Br⁻·H₂O 4, bistriflimide 5) were determined. Short interionic contacts were identified. Cyclic voltammetry of 2 revealed an electrochemical window from +1.0 to −1.5 V with a single Fe(III)/Fe(II) redox event at −0.27 V on a gold electrode versus Ag/AgCl.

【 授权许可】

CC BY   
© 2014 by the authors; licensee MDPI, Basel, Switzerland.