Effect of Temperature on the Growth of Silver Nanoparticles Using Plasmon-Mediated Method under the Irradiation of Green LEDs

Materials

Shan-Wei Lee²  Shi-Hise Chang²  Yen-Shang Lai²  Chang-Cheng Lin²  Chin-Min Tsai²  Yao-Chang Lee²  Jui-Chang Chen¹  Cheng-Liang Huang¹ 

[1] Department of Applied Chemistry, National Chiayi University, Chiayi City 600, Taiwan;

关键词: plasmon-mediated;    silver nanoplates;    silver nanodecahedra;    SERS;   

DOI  :  10.3390/ma7127781

来源: mdpi

【 摘 要 】

Plasmon-mediated shape conversion of spherical silver nanoparticles (NPs) to nanostructures with other shapes under the irradiation of green LEDs (520 ± 20 nm, 35 mw/cm²) at various temperatures (60, 40, 20, 10, 5, and 0 °C) was performed in this study. It was found that the bath temperature used in the reaction can influence the reaction rates, i.e., the times needed for the shape transformation process were 5, 11.5, 25, 45, 72, and 100 h at 60, 40, 20, 10, 5, and 0 °C, respectively. In addition, the bath temperature can also alter the morphologies of the final products. The major products are silver nanoplates at 60, 40 and 20 °C. However, they became decahedral silver NPs at 5 and 0 °C. The percentages of decahedral silver NPs synthesized at 60, 40, 20, 10, 5, and 0 °C are 0%, 1%, 5%, 45%, 73%, and 89%, respectively. Measuring the surface-enhanced Raman spectroscopy (SERS) spectra of the probe molecule R6G in the presence of KBr showed that both silver nanoplate colloids synthesized at 60 °C and decahedral silver NP colloids synthesized at 0 °C in the absence of PVP had good SERS activities.

【 授权许可】

CC BY   
© 2014 by the authors; licensee MDPI, Basel, Switzerland.