TDAE Strategy in the Benzoxazolone Series: Synthesis and Reactivity of a New Benzoxazolinonic Anion

Molecules

A R. Nadji-Boukrouche²  Omar Khoumeri¹  Thierry Terme¹  Messaoud Liacha³  Patrice Vanelle¹ 

[1] Aix-Marseille Université, CNRS, Institut de Chimie Radicalaire ICR, UMR 7273, Laboratoire de Pharmaco-Chimie Radicalaire, Marseille 13385, France; E-Mails:;Département de Génie des Procédés, Université 8 mai 1945 Guelma, BP 401, Guelma 24000, Algeria; E-Mail:;Laboratoire de Synthèse et de Biocatalyse Organique (LSBO), Faculté des Sciences, Université Badji Mokhtar-Annaba, BP 12 El-Hadjar, Annaba 23000, Algeria; E-Mail:

关键词: TDAE;    benzoxazolone;    benzoxazolinonic anion;    benzylic alcohols;    oxiranes;   

DOI  :  10.3390/molecules20011262

来源: mdpi

【 摘 要 】

We describe an original pathway to produce new 5-substituted 3-methyl-6-nitro-benzoxazolones by the reaction of aromatic carbonyl and α-carbonyl ester derivatives with a benzoxazolinonic anion formed exclusively via the TDAE strategy.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.