In Situ EPR Studies of Reaction Pathways in Titania Photocatalyst-Promoted Alkylation of Alkenes

Molecules

Shona Rhydderch²  Russell F. Howe¹  John Walton² 

[1] Chemistry Department, University of Aberdeen, Aberdeen AB24 3UE, UK; E-Mail

关键词: EPR spectroscopy;    titania;    photocatalysis;    alkene alkylation;   

DOI  :  10.3390/molecules20034055

来源: mdpi

【 摘 要 】

In situ EPR spectroscopy at cryogenic temperatures has been used to observe and identify paramagnetic species produced when titania is irradiated in the presence of reactants used in the photocatalytic alkylation of maleimide with t-butyl carboxylic acid or phenoxyacetic acid. It is shown that maleimide acts as an acceptor of conduction band electrons. Valence band holes oxidise t-butyl carboxylic acid to the t-butyl radical and phenoxyacetic acid to the phenoxyacetic acid radical cation. In the presence of maleimide, the phenoxymethyl radical is formed from phenoxyacetic acid. The relevance of these observations to the mechanisms of titania photocatalyst-promoted alkylation of alkenes is discussed.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.