Use of Gypsum as a Preventive Measure for Strength Deterioration during Curing in Class F Fly Ash Geopolymer System

Materials

Yubin Jun²  Jae Eun Oh¹ 

[1] School of Urban and Environmental Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan Metropolitan City 689-798, Korea; E-Mail

关键词: fly ash;    geopolymer;    gypsum;    Na₂SO₄;    strength deterioration;    nanometer-crack;   

DOI  :  10.3390/ma8063053

来源: mdpi

【 摘 要 】

This study discusses strength deterioration during the curing process of fly ash geopolymer and the use of CaSO₄·2H₂O (gypsum) as a deterioration remedy when the ash was synthesized using a 10M NaOH and Na-silicate solution. The strength decline was mainly due to the widespread formation of nanometer-sized cracks that were related to excessive Na and Si concentrations at an early age. Use of 2 wt% CaSO₄·2H₂O resulted in the best measured strength by temporarily reducing Na and Si concentrations; Na was absorbed by SO₄²⁻, up to 11% in the matrix within one day, and formed Na₂SO₄ (thenardite), which gradually dissolved over time, slowly releasing Na ions. However, more than 4% gypsum suppressed overall strength development because too many Na ions were locked into Na₂SO₄ and could not participate in geopolymerization. The addition of gypsum impeded glass dissolution and even halted the process when more than 4% gypsum was used.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.