Selenium-Mediated Synthesis of Tetrasubstituted Naphthalenes through Rearrangement

Molecules

James Tancock²  Thomas Wirth¹ 

[1] School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK; E-Mail

关键词: naphthols;    rearrangement;    selenium;   

DOI  :  10.3390/molecules200610866

来源: mdpi

【 摘 要 】

New β-keto ester substituted stilbene derivatives have been synthesized and cyclized with selenium electrophiles in the presence of Lewis acids. This now allows access to 1,2,3,4-tetrasubstituted naphthalene derivatives as cyclization and rearrangement products.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.