Growth and Characterization of Lead-free Piezoelectric Single Crystals

Materials

Philippe Veber¹  Feres Benabdallah¹  Hairui Liu¹  Gabriel Buse¹  Michael Josse¹  Mario Maglione¹ 

[1] Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB), Unité Propre de Recherche (UPR) 9048, Centre National de la Recherche Scientifique (CNRS), Pessac F-33600, France;

关键词: crystal growth;    lead-free materials;    piezoelectrics;   

DOI  :  10.3390/ma8115436

来源: mdpi

【 摘 要 】

Lead-free piezoelectric materials attract more and more attention owing to the environmental toxicity of lead-containing materials. In this work, we review our first attempts of single crystal grown by the top-seeded solution growth method of BaTiO₃ substituted with zirconium and calcium (BCTZ) and (K_0.5Na_0.5)NbO₃ substituted with lithium, tantalum, and antimony (KNLSTN). The growth methodology is optimized in order to reach the best compositions where enhanced properties are expected. Chemical analysis and electrical characterizations are presented for both kinds of crystals. The compositionally-dependent electrical performance is investigated for a better understanding of the relationship between the composition and electrical properties. A cross-over from relaxor to ferroelectric state in BCTZ solid solution is evidenced similar to the one reported in ceramics. In KNLSTN single crystals, we observed a substantial evolution of the orthorhombic-to-tetragonal phase transition under minute composition changes.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.