Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes

Molecules

Antoine Jobin-Des Lauriers²  Claude Y. Legault¹  Wesley Moran² 

[1] Centre in Green Chemistry and Catalysis, Department of Chemistry, University of Sherbrooke, 2500 boul. de l’Université, Sherbrooke, QC J1K 2R1, Canada

关键词: hypervalent iodine;    (diacetoxyiodo)arenes;    metathesis;   

DOI  :  10.3390/molecules201219874

来源: mdpi

【 摘 要 】

The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between (diacetoxyiodo)arenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access (diacetoxyiodo)arenes. A computational study is provided to rationalize the results observed.

【 授权许可】

CC BY   
© 2015 by the authors; licensee MDPI, Basel, Switzerland.