Esterification of Glycerol with Acetic Acid over Highly Active and Stable Alumina-based Catalysts: A Reaction Kinetics Study

Chemical and biochemical engineering quarterly

P. Biswas¹  S. A. Rane¹  S. M. Pudi¹ 

关键词: glycerol esterification;    Cu-Ni bimetallic catalysts;    SO42–/γ-Al2O3 catalyst;    stability;    DAG and TAG selectivity;   

DOI  :  10.15255/CABEQ.2014.2093

来源: Croatian Society of Chemical Engineers

【 摘 要 】

Abstract The catalytic activity of Cu- or Ni monometallic and Cu-Ni bimetallic (Cu/Ni ratio = 3, 1, 0.33) catalysts supported on γ-Al2O3 and SO42–/γ-Al2O3 catalysts were evaluated for esterification of glycerol. The reactions were performed in a batch reactor under reflux at standard reaction conditions: temperature 110 °C, atmospheric pressure, glycerol to acetic acid molar ratio 1:9, and catalyst loading 0.25 g. The best catalytic activitywas observed over 2 M SO42–/γ-Al2O3 catalyst, which showed the glycerol conversion of 97 % within 2 hours of reaction. At this condition, the selectivity to glyceryl monoacetate (MAG), glyceryl diacetate (DAG), and glyceryl triacetate (TAG) were 27.0%, 49.9 % and 23.1 %, respectively, after 5 h of reaction. After three consecutive runs, the 2 M SO42–/γ-Al2O3 catalysts showed superior performance and no loss in activity was observed. The reaction kinetics results over 2 M SO42–/γ-Al2O3 catalyst showed that the dependence on the reaction rate to glycerol concentration was of pseudo-second order, while the activation energy was found to be 106 kJ mol–1.

【 授权许可】

Unknown